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【结 构 式】

【分子编号】69526

【品名】10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride

【CA登记号】

【 分 子 式 】C15H10Br2ClNO

【 分 子 量 】415.511

【元素组成】C 43.36% H 2.43% Br 38.46% Cl 8.53% N 3.37% O 3.85%

与该中间体有关的原料药合成路线共 1 条

合成路线1

该中间体在本合成路线中的序号:(II)

 

1 Ansari SK,Bhat R,Kulkarni AK, et al.2003.Process for preparation of 10-methoxycarbamazepine by reaction of 10-methoxyiminostilbene with cyanic acid in the presence of weak acid. EP 1302464.
2 Gutman D, Baidossi W. Method of preparation a 5H-dibenz[b,f]azepine-5-carboxamide. WO 2003106414.
3 Muthukumaran M, Natarajan M, Thennati R. 2005.Process for reparation of 10-oxo-10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxamide. WO 2005096709.
4 Parenky C, Chaturvedi R. 2005. Novel process for reparation of 10-oxo-10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxamide(oxcarbazepine) via intermedia, 10-methoxy-5H-dibenz[b,f]azepine-5-carbonyl chloride. WO 2005066133.
5 Schmieder van de Vondervoort L, Bouttemy S, Heu F, et al. 2003. Low temperature, high conversion, liquid-phase benzylic oxidation with dioxygen by metal/NHPI-catalyzed co-oxidation with benzaldehude. European Journal of Organic Chemistry, (3):578-589.
6 Sivakumar BV, Bhirud SB, Batchu C, et al.2005.Preparation of 5H-dibenz[b,f]azepinecarboxamides. US 2005203297.
中间体序号 中间体编号 品名 CAS号 分子式 供应商 用于合成
(I) 69525 Dibenz[b,f]azepine-5-carbonyl chloride;Iminostilbene carbonyl chloride;5-Chlorocarbonyl iminostilbene;5H-dibenzo[b,f]azepine-5-carbonyl chloride 33948-22-0 C15H10ClNO 详情 详情
(II) 69526 10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride C15H10Br2ClNO 详情 详情
(III) 69527 methyl 10-bromo-5H-dibenzo[b,f]azepine-5-carboxylate C16H12BrNO2 详情 详情
(IV) 24333 10-methoxy-5H-dibenzo[b,f]azepine;10-Methoxyiminostilbene 4698-11-7 C15H13NO 详情 详情
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