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【结 构 式】

【分子编号】67039

【品名】(R,Z)-5-methyl-6-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohex-1-enecarbaldehyde

【CA登记号】 

【 分 子 式 】C17H26O3

【 分 子 量 】278.39164

【元素组成】C 73.35% H 9.41% O 17.24%

与该中间体有关的原料药合成路线共 1 条

合成路线1

该中间体在本合成路线中的序号:(IX)

 

1 Avery MA, Chong WKM, Jennings-White C. 1992. Stereoselective total synthesis of (+) -artemisinin, the antimalarial constitutent of Artemisia annua L. J Am Chem Soc, 114(3): 974~979.
中间体序号 中间体编号 品名 CAS号 分子式 供应商 用于合成
(II) 67032 (6R)-2,2,6-trimethyl-1-oxaspiro[2.5]octan-4-one   C10H16O2 详情 详情
(I) 56751 (5R)-5-methyl-2-(1-methylethylidene)cyclohexanone C10H16O 详情 详情
(III) 67033 (5S)-5-methyl-2-(phenylthio)cyclohexanone   C13H16OS 详情 详情
(IV) 67034 (5R)-5-methyl-2-(phenylsulfinyl)cyclohexanone   C13H16O2S 详情 详情
(V) 67035 2-(2-bromoethyl)-2,5,5-trimethyl-1,3-dioxane 87842-52-2 C9H17BrO2 详情 详情
(VI) 67036 (3R,Z)-3-methyl-6-(phenylsulfinyl)-2-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohexanone   C22H30O4S 详情 详情
(VII) 67037 (R,Z)-3-methyl-2-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohexanone   C16H26O3 详情 详情
(VIII) 67038 (Z)-4-methyl-N'-((R,Z)-3-methyl-2-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohexylidene)benzenesulfonohydrazide   C23H34N2O4S 详情 详情
(IX) 67039 (R,Z)-5-methyl-6-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohex-1-enecarbaldehyde   C17H26O3 详情 详情
(X) 67040 ((R,Z)-5-methyl-6-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)cyclohex-1-en-1-yl)(trimethylsilyl)methyl acetate   C22H38O4Si 详情 详情
(XI) 67041 2-((2Z,3Z,4R)-4-methyl-3-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)-2-((trimethylsilyl)methylene)cyclohexyl)acetic acid   C22H38O4Si 详情 详情
(XII) 67042 2-((1R,2Z,3Z,4S)-4-methyl-3-(2-(2,5,5-trimethyl-1,3-dioxan-2-yl)ethylidene)-2-((trimethylsilyl)methylene)cyclohexyl)propanoic acid   C23H40O4Si 详情 详情
Extended Information