【结 构 式】 |
【分子编号】66891 【品名】(2E,4E,6E,8E)-ethyl 3,7-dimethyl-9-(tributylstannyl)nona-2,4,6,8-tetraenoate 【CA登记号】 |
【 分 子 式 】C25H44O2Sn 【 分 子 量 】495.333 【元素组成】C 60.62% H 8.95% O 6.46% Sn 23.96% |
与该中间体有关的原料药合成路线共 1 条
合成路线1
该中间体在本合成路线中的序号: (V)
【1】 D Lera AR, Torrado A, Iglesias B,et aL. 1992. Stereospecifc synthesis of 9-demethylretinoids via palladium-catalyzed vinylboronic acid-vinyl iodide cross coupling. Tetrahedro Lett. 33 (41): 6205~6208 |
【2】 Dominguez B,Iglesias B, de Lera Angle R. 1998. Tetnenylstannanes in the synthesis of retinoic acid anld its ring-modlified analogues. J Org Chem. 63. 4135~4139 |
【3】 Pazas Y, Iglesias B, de Lera Angel R. 2001. The Suzuki coupling reaction in the stereocontrolled synthesis of 9-cis-retinoic acid and its ring-demethylated anaIoguer. J Ore Chem,66(25): 8483~8489(有关9-顺式一维A酸及其衍生物的合成) |
【4】 Trost BM, Sorum MT, Chan C. et aL. 1997. Palladium-catalyzed additions of terminal alkynes to acceptor alkynes, J Am Chem Soc, 119: 698~708 |
中间体序号 | 中间体编号 | 品名 | CAS号 | 分子式 | 供应商 | 用于合成 |
---|---|---|---|---|---|---|
(V) | 66891 | (2E,4E,6E,8E)-ethyl 3,7-dimethyl-9-(tributylstannyl)nona-2,4,6,8-tetraenoate | C25H44O2Sn | 详情 | 详情 | |
(I) | 65494 | 2,2,6-Trimethylcyclohexanone | C9H15O | 详情 | 详情 | |
(II) | 66889 | 2,6,6-trimethylcyclohex-1-en-1-yl trifluoromethanesulfonate | C10H15F3O3S | 详情 | 详情 | |
(III) | 65492 | C18H34OSn | 详情 | 详情 | ||
(IV) | 44704 | ethyl (E)-4-(diethoxyphosphoryl)-3-methyl-2-butenoate | 41891-54-7 | C11H21O5P | 详情 | 详情 |
Extended Information