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【结 构 式】 
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【分子编号】26407 【品名】 【CA登记号】 |
【 分 子 式 】C106H144Br2Cl2I2O29S2SeSi3 【 分 子 量 】2594.1628 【元素组成】C 49.08% H 5.59% Br 6.16% Cl 2.73% I 9.78% O 17.89% S 2.47% Se 3.04% Si 3.25% |
与该中间体有关的原料药合成路线共 1 条
合成路线1
该中间体在本合成路线中的序号：(IX)The elimination of the diol protecting group of compound (VIII) with CSA in methanol followed by silylation with TES triflate affords the silylated pentasaccharide (IX), which is finally desulfurized and deiodinated by hydrogenolysis with Et3B and Bu3SnH, and with RaNi to eliminate also the BOM protecting group, and with FH in pyridine to eliminate the silyl and chloroacetyl groups affording the target olivomycin A.
Extended Information